2023

Chemistry Günther Schlonk Chemistry Günther Schlonk

The Structural Determination, Total Synthesis and Endochronicity of Thiotimoline

The natural product thiotimoline was isolated from the bark of Rosaceae Karlsbadensis rufo and its structure was unambiguously determined by time-resolved X-ray crystallomancy and spectroscopy. A total synthesis of thiotimoline was conducted following a convergent strategy. The pivotal transformations in this synthesis were a tandem Suzuki-Miyaura/Schinkenfaust radical cross-spifflication, a Szymankowszczyzna allylic inquisition and a [3+2+3+2] Puccini-Gershwin echocyclisation in A♭ major. An unnatural isomer of thiotimoline was also synthesised, and a theory of kairality and chronomers is presented and discussed.

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Chemistry Günther Schlonk Chemistry Günther Schlonk

Synthesis and Characterization of a Novel Nitrotoluene Polymer: TNTP

The attractive physical properties and widespread availability of 2,4,6-trinitrotoluene (TNT) make it a popular commodity chemical. In accordance with the maxim that longer things are more appealing, it stands to reason that polymerising TNT should improve its utility. Herein, we report the first synthesis of poly(TNT), and an appraisal of its properties and commercial potential.

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Materials Science Günther Schlonk Materials Science Günther Schlonk

Synthesis and Characterisation of a Slightly-Above-Room-Temperature Superconductor

The search for a material capable of conducting electricity without resistance at room temperature and atmospheric pressure has preoccupied scientists for more than a century. Such a material has as unrivalled capacity to produce platitudes and hyperbole from science communicators and journalists, as well as some minor implications for the electronics and power industries. Herein, we report the synthesis and characterisation of such a material: a cobalt-doped uranic corium called SK-431.

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Chemistry Günther Schlonk Chemistry Günther Schlonk

On the Bending of SPOONS

The following article constitutes a preliminary trial of a chemistry-specific artificial intelligence chatbot called “ChatCsp3”. This bot is being trained to take dense chemical jargon (left column) and make it accessible to the general public (right column).

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Mathematics Günther Schlonk Mathematics Günther Schlonk

An Algorithm for Faster Sock Sorting

Sorting socks can often be a time-consuming task. This paper introduces the fastest method known in the scientific community to tackle this challenging task. Details required to implement the new algorithm and data structure will be introduced and discussed. Abundant application of this novel algorithm may be able to reduce the time required for sorting socks considerably.

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Blockchain Günther Schlonk Blockchain Günther Schlonk

Proof of Wankery: A Novel Consensus Model for the Blockchain

Proof of Work is killing the planet, Proof of Stake is a pyramid scheme, and other proposed consensus models are either easy to spoof or infeasible to implement. Herein, a new model is proposed: Proof of Wankery (PoWank). PoWank does away with the problems of weighted voting by digital assets or wasted work, and instead awards votes based on an individual’s ongoing dedication to the #Web3 lifestyle. 

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Chemistry Günther Schlonk Chemistry Günther Schlonk

The Total Synthesis of Monoalizeamine D

We report the first total synthesis of the supernatural product monoalizeamine D via a 14-step pathway. Our synthetic approach relies heavily on photocatalysis and radical intermediates. By preparing both E and Z isomers of this compound, we have conclusively resolved the ambiguity concerning the orientation of the C15–C16 olefin.

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