Platinum-Group Based Pentazolatocarboxylate MILFs for Direct CO2 Capture and Solar Fuel Applications

Abstract: We report the preparation of a PtO-pentazole Metal Inorganically Linked Framework (MILF). This MILF was characterised by PXRD and elemental analysis, and exhibits pronounced host-guest interactions, stimulus-response behaviour, and high internal surface area. The material also shows promise as a catalyst for the conversion of CO2 to octane.