2021 (work in progress)
A Simplistic Model of Stress-Development During PhD Candidature
We demonstrate an abundance of useful properties in particular combinations of period-7 elements.
Superconductivity, Superfluidity, Supersymmetry, and Superspectacularity in Atomically Pure DbNh2Mc2
We demonstrate an abundance of useful properties in particular combinations of period-7 elements.
Proposed Detection of Ghosts by Mass Spectrometry-Spectral Presence Origin-Omics Kinetic Yield (MS-SPOOKY)
Ghost hunting has yet to consider the realm of laboratory instrumentation for detection and visualization of ghosts. Here I describe the potential application of a ubiquitous piece of equipment in research settings, the mass spectrometer, that can be co-opted for detection of apparitions.
The Smythe Reagent: ~1.6 M LiOH in Hexane
The Smythe reagent is an approximately 1.6 M suspension of LiOH in hexane, and is ubiquitous in synthetic chemistry laboratories worldwide. While commercially available, it is more frequently prepared from n-butyllithium, usually by accident. We describe a range of applications for this reagent, such as the O-lithiation of carboxylic acids, hydrolysis of ethyl esters and chlorophosphines, racemisation of alpha-stereocenters and poly-Claisen condensations.
Platinum-Group Based Pentazolatocarboxylate MILFs for Direct CO2 Capture and Solar Fuel Applications
We report the preparation of a PtO-pentazole Metal Inorganically Linked Framework (MILF). This MILF was characterised by PXRD and elemental analysis, and exhibits pronounced host-guest interactions, stimulus-response behaviour, and high internal surface area. The material also shows promise as a catalyst for the conversion of CO2 to octane.
A Partial Total Synthesis of Impracticatechol
An elegant procedure for the progression towards the total synthsis of Impracticatechol is presented. The importance of this work is such that we reserve the right for further miscommunications in this field.
Spectroscopy Confirms that Victorian Bitter is Vinegar.
Some troubling results from the analysis lab.
Methyl Ethyl Butyl Futyl
Eveyone who has spent more than a year in the field of organic chemistry has heard the refrain: methyl ethyl butyl futile. This joke underligns the point of diminishing returns which is reached when making analogues of the same molecule. Because of this joke, the versatile chemistry of the futyl group has been overshadowed. This review highlights some examples in the history and applications of the futyl group.
An Informal Synthesis of an En-yn-en-yn-ol
The first ever paper in The Journal of Immaterial Science.
Novel Magnesium-Based Chlorin for Efficient Catalytic Reduction of CO2
Utilisation of CO2 has historically been done via catalytic conversion into methane or syngas. Such a process involves the use of inorganic and potentially environmental-unfriendly metals while the products are also not biodegradable. Much safer alternatives are proposed in this paper. It is discovered that the introduction of trace Mg2+ into a solution of Chlorin A (Figure 1) results in a catalyst capable of reducing CO2 into various polyalcohols, the latter being energy sources for many organisms.
Chemical Frenetics: Party Drugs as Organocatalysts
We have tested a range of recreational drugs as organocatalysts in the Fukovski Combobulation. Most of the tested drugs are detrimental to the reaction, but cocaine shows promise as a catalyst, with the appropriate dosage. The mechanistic roles of these molecules are probed with chemical frenetic measurements and Density Dysfunctional Theory (DDT).
PPG: Personal Protective Groups as a Defence Against Laboratory Carcinogens
An examination of the conformers of oldmacdenynenynol.
Basketane Carrying Capacity and a Closer Look at the Atom Economy
One can’t judge a book by its cover, but one can judge a reaction by its colour.
50 Shades of Brown: An Index of Chemical Misery
One can’t judge a book by its cover, but one can judge a reaction by its colour.